The song, called Writing’s On The Wall, has been co-written by Sam Smith and was recorded in January.
Spectre will be released in the US on November 6.
On September 7, Sam Smith posted a photograph of his hand wearing a ring with the movie’s Spectre logo on it.
Writing’s On The Wall will be available to buy and stream from September 25.
The song was also co-written by Jimmy Napes who has previously collaborated with Sam Smith on tracks including Stay With Me and Lay Me Down.
Previous James Bond themes have been sung by Adele (Skyfall), Madonna (Die Another Day), Sheryl Crow (Tomorrow Never Dies) and Shirley Bassey (Goldfinger, Diamonds Are Forever and Moonraker).
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