Thousands of migrants traveled to the Austrian border by bus, by train and on foot before moving on to Vienna and Munich.
Austrian officials are laying on more trains as needed.
German Chancellor Angela Merkel is to hold talks with her coalition partners on a crisis that has divided the EU.
After days of confrontation and chaos, Hungary opened its borders with Austria and bussed thousands of migrants to the frontier.
Up to 10,000 arrived at the border on September 5, according to the Austrian authorities, who have said they do not plan to limit the numbers crossing into the country.
Many traveled straight on to Munich, southern Germany, where locals greeted them with applause, giving sweets to the children among the new arrivals.
They have been sent on to reception centers to be registered and receive food and clothing.
Both Germany and Hungary have said the current measures are aimed at averting a humanitarian crisis, and will not set a precedent.
The rules requiring refugees to apply for asylum in the first country they land in “are still valid, and we expect other European Union member states to stick to them”, a German government spokesman said.
Chancellor Angela Merkel has said Germany can cope with the influx of newcomers without raising taxes or jeopardizing its budget.
Germany is the key destination for arrivals on European shores, and expects to take in 800,000 people this year.
Syrians fleeing a brutal civil conflict are the largest group travelling, followed by Afghans and Eritreans.
There is little sign of a co-ordinated EU response to the crisis, despite more than 350,000 migrants having crossed the EU’s borders in 2015 alone.
Germany, backed by the European Commission, has been pushing for a quota system for dividing the people reaching Europe between member states.
However, this has been opposed by several eastern members.
On September 5, Hungary said that while it had temporarily relaxed restrictions on the transit of asylum seekers, it was pressing ahead with plans to tighten border controls and could send troops to its southern frontier if parliament agreed.
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